• editor.aipublications@gmail.com
  • Track Your Paper
  • Contact Us
  • ISSN: 2456-866X

International Journal Of Chemistry, Mathematics And Physics(IJCMP)

Synthesis, Characterization and Dielectric properties of Nanoparticles of Cobalt Doped Ferrite (Cox Fe1-x Fe2 O4)

Priyanka Gupta , Dr. Ravi Kumar Vijai


International Journal of Chemistry, Mathematics And Physics(IJCMP), Vol-7,Issue-4, July - August 2023, Pages 1-8 , 10.22161/ijcmp.7.4.1

Download | Downloads : 1 | Total View : 393

Article Info: Received: 03 May 2023; Received in revised form: 03 Jul 2023; Accepted: 11 Jul 2023; Available online: 19 Jul 2023

Share

Ferrites, a recently uncovered category of materials, have found extensive application in various critical domains. Among them, cobalt ferrites stand out as hard magnetic materials with exceptional coercivity.. We successfully prepared cobalt ferrites by using nanocrystalline powers by Sol gel method. In our study Crystalline, Magnetic nanoparticles of Cobalt ferrites (Cox Fe1-x Fe2 O4) (x = 0.4, 0.5, 0.6, 0.8) were synthesized by Sol Gel Method using ferric chloride and cobalt nitrate with NaOH as a reactant. Structural characteristics of samples were determined by X-Ray diffraction and TEM. Particle size found between 8.8 nm to 14.26 nm using Debye Scherrer method. Lattice constant decreases as the value of ‘x’ increases. Dielectric properties were investigated using impedance analyser. The relative dielectric constant and loss tangents of ferrites a function of frequency (1kHz-30MHz) was investigated at room temperature, both parameter decreases as frequency increases.

Cobalt ferrites, Dielectric constant, Impedance analyser, Nanoparticles, XRD

[1] Wu M Z, He H H, Zhao Z S and Yao X 2000 Electromagnetic and microwave absorbing properties of iron fibre–epoxy resin composites J Phys D: Appl Phys 33 2398-2401
[2] Wei J, Liu J H and Li S M 2007 Electromagnetic and microwave absorption properties of Fe3O4 magnetic films plated on hollow glass spheres J Magn Magn Mater 312 414-417
[3] Ohlan A, Singh K, Chandra A and Dhawan S K 2008 Microwave absorption properties of conducting polymer composite with barium ferrite nanoparticles in 12.4–18 GHz Appl Phys Lett 93 053114
[4] Moya C, del Puerto Morales M, Batlle X, Labarta A. Tuning the magnetic properties of co-ferrite nanoparticles through the 1,2-hexadecanediol concentration in the reaction mixture. Physical Chemistry Chemical Physics. 2015;17:13143-13149.
[5] Keluskar SH, Tangsali RB, Naik GK, Budkuley JS. High permeability of low loss Mn-Zn ferrite obtained by sintering nanoparticle Mn-Zn ferrite. J. Magn. Magn. Mater. 2006;305:296-303.
[6] Shobana, M.K., Sankar, S.: J. Magn. Magn. Mater. 321, 599–601 (2009)
[7] Verma, K.; Kumar, A.; Varshney, D. Dielectric relaxation behavior of A x Co 1− x Fe 2 O 4 (A= Zn, Mg) mixed ferrites. Journal of Alloys and Compounds. 2012,526, 91-97
[8] Lv, W.-Z., Liu, B., Luo, Z.-K., Ren, X.-Z., Zhang, P.-X.: J. Magn. Magn. Mater. 321, 599–601 (2009)
[9] Wang, J., Chong, P.F., Ng, S.C., Gan, L.M.: Mater. Lett. 30, 217–221 (1997)
[10] Arjunwadkar, P.R., Patil, R.R., Kulkarni, D.K.: J. Alloys Compd. 463, 403–407 (2008)
[11] Huo, J., Wei, M.: Mater. Lett. 63, 1183–1184 (2009)
[12] Verwey E J W, Haaijman P W, Romeyn F C and Van Oosterhout G M 1950 Phil. Res. Rep. 5 173.
[13] Ponpandian N, Balaya P and Narayanasamy A 2002 J. Phys. Condens. Matter 14 3221.
[14] Mahajan P R, Patankar K K, Kothale M B, Chaudhari S C, Mathe V L and Patil S A 2002 Pramana 58 1115.
[15] Jonker G H 1959 J. Phys. Chem. Solids 9 165.
[16] Na J G, Lee T D and Park S J 1992 IEEE Trans. Magn. 28 2433.
[17] Na J G, Kim M C, Lee T D and Park S J 1993 IEEE Trans. Magn. 29 3520.
[18] 18.B. D. Cullity, Elements of X-Ray Diffraction, Addison-Wesley, London, UK, 2nd edition, 1978.
[19] Babukutty B, Kalarikkal N, Nair SS. Studies on structural, optical and magnetic properties of cobalt substituted magnetite fluids (CoxFe1-xFe2O4). Materials Research Express. 2017 Mar 1;4(3).
[20] Soleimani H, Ahmad Latiff NR, Zaid HM, Yahya N, Sadrolhosseini AR, Adil M. Effect of synthesis parameters on cobalt ferrite saturation magnetization. In: Journal of Physics: Conference Series. Institute of Physics Publishing; 2018.
[21] A Flores G, O B, S Martínez V, L De La Cruz M, C Patiño C. Synthesis and Characterization of Cobalt Ferrite CoxFe3-xO4 Nanoparticles by Raman Spectroscopy and X-Ray Diffraction.
[22] International Journal of Metallurgy and Metal Physics. 2020 Mar 31;5(1).
[23] Wanger, K.W.: Ann. Phys. 40, 817(1913).
[24] Rabinkin, I.T., Novikova, Z.I.: Ferrites. Izv. Acad. Nauk USSr, Minsk (1960), pp146.
[25] Tasawar J., Asghari M., Akhlaq A. M., J. Supercond Nov Magn (2011) 24, 2137 (2011).
[26] Yadav RS, Kuřitka I, Vilcakova J, Havlica J, Masilko J, Kalina L, et al. Impact of grain size and structural changes onmagnetic, dielectric, electrical, impedance and modulus spectroscopic characteristics of CoFe2O4nanoparticles synthesized by honey mediated sol-gel combustion method. Advances in Natural Sciences: Nanoscience and Nanotechnology. 2017 Dec 1;8(4).